The grinding beakers (45 mL; agate) were equipped with 6 milling balls of the same material (d = 15 mm). Alkyl but2ynedioate 1 (1 mmoL), amine 2 (1 mmoL), NaAuCl 2 O (1 mol%) were added in the given order and ballmilled quickly for 1 min at 400 rpm. Then to this mixture was added another amine 2 (1 mmoL) and